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dc.contributor.author
 hal.structure.identifier
BELLILI, Amar
133667 NEXANS RESEARCH CENTER [NRC]
dc.contributor.authorDAVID, Nicolas
dc.contributor.authorWANG, Qingxiao
dc.contributor.author
 hal.structure.identifier
GOUTILLE, Yannick
133667 NEXANS RESEARCH CENTER [NRC]
dc.contributor.author
 hal.structure.identifier
RICHAUD, Emmanuel
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
dc.date.accessioned2015
dc.date.available2015
dc.date.issued2012
dc.date.submitted2015
dc.identifier.issn0142-9418
dc.identifier.urihttp://hdl.handle.net/10985/10084
dc.description.abstractThis paper reports a study of mineral oil diffusion through a filled ethylene-vinyl acetate crosslinked polymer, together with some comparisons with aliphatic linear hydrocarbons. Permeation was monitored by classical gravimetric measurements leading to values of solubility and diffusion coefficient at several temperatures ranging from 20 to 120 °C. Diffusion coefficients display a change in activation energy at at ca. 70 °C for mineral oils but not for simple hydrocarbons. The values obtained were discussed regarding available structure-diffusivity relationships and diffusion models derived from free volume theory. A relationship between penetrant evaporation temperature and its diffusivity was observed and tentatively justified.
dc.language.isoen
dc.publisherElsevier
dc.rightsPost-print
dc.subjectEVA copolymer
dc.subjectMineral oil
dc.subjectDiffusion
dc.subjectSolubility
dc.subjectModelling
dc.subjectActivation energy
dc.titleDiffusion and solubility of mineral oils through ethylene-vinyl acetate copolymer
dc.identifier.doi10.1016/j.polymertesting.2011.11.003
dc.typdocArticle dans une revue avec comité de lecture
dc.localisationCentre de Paris
dc.subject.halChimie: Polymères
dc.subject.halSciences de l'ingénieur: Matériaux
dc.subject.halSciences de l'ingénieur: Mécanique
ensam.audienceInternationale
ensam.page236–247
ensam.journalPolymer Testing
ensam.volume31
hal.identifierhal-01202709
hal.version1
hal.statusaccept


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