An experimental and analytical study of the elasticity of model polyurethane networks crosslinked by tri- and quadriisocyanate
dc.contributor.author | GILORMINI, Pierre |
dc.contributor.author | DIANI, Julie |
dc.contributor.author
hal.structure.identifier | FAYOLLE, Bruno
|
dc.date.accessioned | 2013 |
dc.date.available | 2013 |
dc.date.issued | 2010 |
dc.date.submitted | 2013 |
dc.identifier.issn | 0303-402X |
dc.identifier.uri | http://hdl.handle.net/10985/6814 |
dc.description | The original publication is available at www.springerlink.com : http://link.springer.com/article/10.1007%2Fs00396-009-2145-6?LI=true |
dc.description.abstract | Polyurethane networks have been prepared from a mix of tri- and quadriisocyanate and from two types of diols, polyether-based (with molar masses of 1,000, 2,000, and 4,000 g/mol) and polyester-based (1,035 g/mol). The weight fraction of sol has been measured, as well as the elastic shear modulus of the gels. It has been found that the statistical theory of network formation predicts a weight fraction of sol in agreement with the experimental results, but its standard combination with the theory of rubber elasticity disagrees significantly with the elastic modulus measured. This suggests a discrepancy between theory and experiment in terms of elastically active chains. In contrast, the assumption that all nodes in the gel, or even in the system, are elastically active gives much better predictions for the system considered. |
dc.description.sponsorship | ANR JCJC MELAC |
dc.language.iso | en |
dc.publisher | Springer Verlag |
dc.rights | Post-print |
dc.subject | Polyurethane |
dc.subject | Model networks |
dc.subject | Rubber elasticity |
dc.title | An experimental and analytical study of the elasticity of model polyurethane networks crosslinked by tri- and quadriisocyanate |
dc.identifier.doi | 10.1007/s00396-009-2145-6 |
dc.typdoc | Article dans une revue avec comité de lecture |
dc.localisation | Centre de Paris |
dc.subject.hal | Sciences de l'ingénieur: Mécanique: Mécanique des matériaux |
ensam.audience | Internationale |
ensam.page | 97-103 |
ensam.journal | Colloid and Polymer Science |
ensam.volume | 288 |
hal.identifier | hal-00794193 |
hal.version | 1 |
hal.status | accept |
dc.identifier.eissn | 1435-1536 |