Co-oxidation kinetic model for the thermal oxidation of polyethylene-unsaturated substrate systems
dc.contributor.author | VERDU, Jacques |
dc.contributor.author | RYCHLÝ, Jozef |
dc.contributor.author
hal.structure.identifier | FAYOLLE, Bruno
|
dc.contributor.author | RICHAUD, Emmanuel |
dc.date.accessioned | 2014 |
dc.date.available | 2014 |
dc.date.issued | 2013 |
dc.date.submitted | 2014 |
dc.identifier.issn | 0141-3910 |
dc.identifier.uri | http://hdl.handle.net/10985/8197 |
dc.description.abstract | The thermal oxidation of polyethylene (PE) impregnated by the methyl esters of unsaturated fatty acids (UFEs) was studied using chemiluminescence, and infra-red spectrophotometry. It was shown that the presence of UFEs accelerates the PE aging process. This can be interpreted as a co-oxidation phenomenon. In this study, the previously established models for PE and UFEs self-oxidation have been coupled in order to develop a co-oxidation model. Using the existing rate constants for the PE and UFEs selfoxidations, this model can simulate the complex shape of the kinetic curves of PE-UFE co-oxidation |
dc.language.iso | en |
dc.publisher | Elsevier |
dc.rights | Post-print |
dc.subject | Polyethylene |
dc.subject | Methyl esters of unsaturated fatty acids |
dc.subject | Co-oxidation |
dc.subject | Kinetic modeling |
dc.subject | Chemiluminescence |
dc.title | Co-oxidation kinetic model for the thermal oxidation of polyethylene-unsaturated substrate systems |
dc.identifier.doi | 10.1016/j.polymdegradstab.2013.01.008 |
dc.typdoc | Article dans une revue avec comité de lecture |
dc.localisation | Centre de Paris |
dc.subject.hal | Chimie: Polymères |
dc.subject.hal | Sciences de l'ingénieur: Matériaux |
dc.subject.hal | Sciences de l'ingénieur: Mécanique |
ensam.audience | Internationale |
ensam.page | 1081-1088 |
ensam.journal | Polymer Degradation and Stability |
ensam.volume | 98 |
hal.identifier | hal-00996704 |
hal.version | 1 |
hal.status | accept |
dc.identifier.eissn | 1873-2321 |