Comparison of stabilization by Vitamin E and 2,6-di-tert-butylphenols during polyethylene radio-thermal-oxidation
dc.contributor.author
hal.structure.identifier | RICHAUD, Emmanuel
|
dc.date.accessioned | 2014 |
dc.date.available | 2014 |
dc.date.issued | 2014 |
dc.date.submitted | 2014 |
dc.identifier.issn | 0969-806X |
dc.identifier.uri | http://hdl.handle.net/10985/8345 |
dc.description.abstract | This paper reports a compilation of data for PE+Vitamin E and 2,6-di-tert-butylphenols oxidation in radio-thermal ageing. Data unambiguously show that Vitamin E reacts with P° and POO° whereas 2,6-di-tert-butyl phenols only react with POO°. Kinetic parameters of the stabilization reactions for both kinds of antioxidants were tentatively extracted from phenol depletion curves, and discussed regarding the structure of the stabilizer. They were also used for completing an existing kinetic model used for predicting the stabilization by antioxidants. This one permits to compare the efficiency of stabilizer with dose rate or sample thickness. |
dc.language.iso | en_US |
dc.publisher | Elsevier |
dc.rights | Post-print |
dc.subject | Polyethylene |
dc.subject | Radio-thermal oxidation |
dc.subject | Vitamin E |
dc.subject | Phenolic antioxidants |
dc.subject | Kinetic analysis |
dc.title | Comparison of stabilization by Vitamin E and 2,6-di-tert-butylphenols during polyethylene radio-thermal-oxidation |
dc.identifier.doi | 10.1016/j.radphyschem.2014.05.053 |
dc.typdoc | Article dans une revue avec comité de lecture |
dc.localisation | Centre de Paris |
dc.subject.hal | Chimie: Matériaux |
dc.subject.hal | Chimie: Polymères |
dc.subject.hal | Sciences de l'ingénieur: Matériaux |
ensam.audience | Internationale |
ensam.page | 158-166 |
ensam.journal | Radiation Physics and Chemistry |
ensam.volume | 103 |
hal.identifier | hal-01024442 |
hal.version | 1 |
hal.status | accept |