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<title>SAM</title>
<link>https://sam.ensam.eu:443</link>
<description>The DSpace digital repository system captures, stores, indexes, preserves, and distributes digital research material.</description>
<pubDate xmlns="http://apache.org/cocoon/i18n/2.1">Thu, 18 Jun 2026 04:26:25 GMT</pubDate>
<dc:date>2026-06-18T04:26:25Z</dc:date>
<item>
<title>A contact area function for Berkovich nanoindentation : Application to hardness determination of a TiHfCN thin ﬁlm</title>
<link>http://hdl.handle.net/10985/8559</link>
<description>A contact area function for Berkovich nanoindentation : Application to hardness determination of a TiHfCN thin ﬁlm
CHICOT, Didier; YETNA N'JOCK, M.; PUCHI-CABRERA, Eli-Saul; IOST, Alain; STAIA, M.H.; LOUIS, G.; BOUSCARRAT, G.; AUMAITRE, R.
In nanoindentation, especially at very low indenter displacements, the indenter/material contact area must be deﬁned in the best possible way in order to accurately determine the mechanical properties of the material. One of the best methodologies for the computation of the contact area has been proposed by Oliver and Pharr [W.C.Oliver, G.M.Pharr, J.Mater. Res. 7 (1992) 1564], which involves a complex phenomenological area function. Unfortunately, this formulation is only valid when the continuous stiffness measurement mode is employed. For other conditions of indentation, different contact area functions, which take into account the effective truncation length or the radius of the rounded indentertip, as well as some ﬁtting parameters, have been proposed. However, most of these functions require a calibration procedure due to the presence of such parameters. To avoid such a calibration, in the present communication a contact area function only related to the truncation length representative of the indenter tip defect, which can be previously estimated with high resolution microscopy, has been proposed. This model allows the determination of consistent indentation data from indenter displacements of only few nanometers indepth. When this proposed contact area function is applied to the mechanical characterization of a TiHfCN ﬁlm of 2.6 μm in thickness deposited onto a tool steel substrate, the direct determination of the hardness and elastic modulus of the ﬁlm leads to values of 35.5±2 GPa and 490±50 GPa, respectively.
</description>
<pubDate>Wed, 01 Jan 2014 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/8559</guid>
<dc:date>2014-01-01T00:00:00Z</dc:date>
<dc:creator>CHICOT, Didier</dc:creator>
<dc:creator>YETNA N'JOCK, M.</dc:creator>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:creator>STAIA, M.H.</dc:creator>
<dc:creator>LOUIS, G.</dc:creator>
<dc:creator>BOUSCARRAT, G.</dc:creator>
<dc:creator>AUMAITRE, R.</dc:creator>
<dc:description>In nanoindentation, especially at very low indenter displacements, the indenter/material contact area must be deﬁned in the best possible way in order to accurately determine the mechanical properties of the material. One of the best methodologies for the computation of the contact area has been proposed by Oliver and Pharr [W.C.Oliver, G.M.Pharr, J.Mater. Res. 7 (1992) 1564], which involves a complex phenomenological area function. Unfortunately, this formulation is only valid when the continuous stiffness measurement mode is employed. For other conditions of indentation, different contact area functions, which take into account the effective truncation length or the radius of the rounded indentertip, as well as some ﬁtting parameters, have been proposed. However, most of these functions require a calibration procedure due to the presence of such parameters. To avoid such a calibration, in the present communication a contact area function only related to the truncation length representative of the indenter tip defect, which can be previously estimated with high resolution microscopy, has been proposed. This model allows the determination of consistent indentation data from indenter displacements of only few nanometers indepth. When this proposed contact area function is applied to the mechanical characterization of a TiHfCN ﬁlm of 2.6 μm in thickness deposited onto a tool steel substrate, the direct determination of the hardness and elastic modulus of the ﬁlm leads to values of 35.5±2 GPa and 490±50 GPa, respectively.</dc:description>
</item>
<item>
<title>Sliding wear of a-C:H coatings against alumina in corrosive media</title>
<link>http://hdl.handle.net/10985/8560</link>
<description>Sliding wear of a-C:H coatings against alumina in corrosive media
STAIA, M.H.; PUCHI-CABRERA, Eli-Saul; IOST, Alain; CARRASQUERO, E.; SANTANA, Y.Y.; LA BARBERA-SOSA, J.G.; CHICOT, Didier; VAN GORP, Adrien
This paper reports the results obtained from the study of friction and sliding wear in two corrosive solutions of an a-C:H coating deposited on 316L stainless against an alumina ball, employed as static counter part. Calculations of the values of the von Mises stresses developed at the coating–substrate interface, as soon as the ball touches the coated sample, and how this state of stress inﬂuences the response of the coated system under the corrosion environment, are presented and discussed. The results obtained from these calculations, as well as from the experiments conducted in the present research, are compared with other experiments published in the literature, where a-C:H coatings deposited on different substrates and with different coating architectures were tested in similar corrosive media. It has been determined that in those systems, where the von Mises stress in the coating, found in the vicinity of the interface, exceeds the threshold value of approximately 370MPa, coating failure with spallation will take place, regardless of the substrate nature on which this coating has been deposited. From this analysis it has been concluded that the coating yield strength is of utmost importance in conferring the a-C:H coated system there quired stability in a corrosive solution.
</description>
<pubDate>Tue, 01 Jan 2013 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/8560</guid>
<dc:date>2013-01-01T00:00:00Z</dc:date>
<dc:creator>STAIA, M.H.</dc:creator>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:creator>CARRASQUERO, E.</dc:creator>
<dc:creator>SANTANA, Y.Y.</dc:creator>
<dc:creator>LA BARBERA-SOSA, J.G.</dc:creator>
<dc:creator>CHICOT, Didier</dc:creator>
<dc:creator>VAN GORP, Adrien</dc:creator>
<dc:description>This paper reports the results obtained from the study of friction and sliding wear in two corrosive solutions of an a-C:H coating deposited on 316L stainless against an alumina ball, employed as static counter part. Calculations of the values of the von Mises stresses developed at the coating–substrate interface, as soon as the ball touches the coated sample, and how this state of stress inﬂuences the response of the coated system under the corrosion environment, are presented and discussed. The results obtained from these calculations, as well as from the experiments conducted in the present research, are compared with other experiments published in the literature, where a-C:H coatings deposited on different substrates and with different coating architectures were tested in similar corrosive media. It has been determined that in those systems, where the von Mises stress in the coating, found in the vicinity of the interface, exceeds the threshold value of approximately 370MPa, coating failure with spallation will take place, regardless of the substrate nature on which this coating has been deposited. From this analysis it has been concluded that the coating yield strength is of utmost importance in conferring the a-C:H coated system there quired stability in a corrosive solution.</dc:description>
</item>
<item>
<title>Analysis of indentation size effect in copper and its alloys</title>
<link>http://hdl.handle.net/10985/8662</link>
<description>Analysis of indentation size effect in copper and its alloys
CHICOT, Didier; PUCHI-CABRERA, Eli-Saul; IOST, Alain; STAIA, M.H; DECOOPMAN, Xavier; ROUDET, F.; LOUIS, G.
For describing the indentation size effect (ISE), numerous models, which relate the load or hardness to the indent dimensions, have been proposed. Unfortunately, it is still difficult to associate the different parameters involved in such relationships with physical or mechanical properties of the material. This is an unsolved problem since the ISE can be associated with various causes such as workhardening, roughness, piling-up, sinking-in, indenter tip geometry, surface energy, varying composition and crystal anisotropy. For interpreting the change in hardness with indent size, an original approach is proposed on the basis of composite hardness modelling together with the use of a simple model, which allows the determination of the hardness–depth profile. Applied to copper and copper alloys, it is shown that it is possible to determine the maximum hardness value reached at the outer surface of the material and the distance over which both the ISE and the workhardening take place.
</description>
<pubDate>Tue, 01 Jan 2013 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/8662</guid>
<dc:date>2013-01-01T00:00:00Z</dc:date>
<dc:creator>CHICOT, Didier</dc:creator>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:creator>STAIA, M.H</dc:creator>
<dc:creator>DECOOPMAN, Xavier</dc:creator>
<dc:creator>ROUDET, F.</dc:creator>
<dc:creator>LOUIS, G.</dc:creator>
<dc:description>For describing the indentation size effect (ISE), numerous models, which relate the load or hardness to the indent dimensions, have been proposed. Unfortunately, it is still difficult to associate the different parameters involved in such relationships with physical or mechanical properties of the material. This is an unsolved problem since the ISE can be associated with various causes such as workhardening, roughness, piling-up, sinking-in, indenter tip geometry, surface energy, varying composition and crystal anisotropy. For interpreting the change in hardness with indent size, an original approach is proposed on the basis of composite hardness modelling together with the use of a simple model, which allows the determination of the hardness–depth profile. Applied to copper and copper alloys, it is shown that it is possible to determine the maximum hardness value reached at the outer surface of the material and the distance over which both the ISE and the workhardening take place.</dc:description>
</item>
<item>
<title>Fatigue behavior of a structural steel coated with a WC–10Co–4Cr/Colmonoy 88 deposit by HVOF thermal spraying</title>
<link>http://hdl.handle.net/10985/9666</link>
<description>Fatigue behavior of a structural steel coated with a WC–10Co–4Cr/Colmonoy 88 deposit by HVOF thermal spraying
LA BARBERA-SOSA, J.G.; SANTANA, Y.Y.; VILLALOBOS-GUTIERREZ, C.; CHICOT, Didier; LESAGE, J.; DECOOPMAN, Xavier; IOST, Alain; STAIA, M.H.; PUCHI-CABRERA, Eli-Saul
The fatigue behavior of a SAE 4340 steel, coated with a 50% WC–10Co–4Cr/50% Colmonoy 88 deposit, by high velocity oxygen fuel (HVOF) thermal spray, has been investigated. The change in the maximum alternating stress with the number of cycles to fracture has been described by means of the relationship advanced by Stromeyer. A fractographic analysis has been carried out on some representative fracture surfaces, by means of scanning electron microscopy (SEM) techniques. The mechanical properties of the coating were characterized by means of nanoindentation tests. The results indicate that the coating is highly heterogeneous. Its deposition gives rise to a decrease in the fatigue strength of the substrate of ∼ 30%, in comparison with the uncoated substrate. The decrease in fatigue strength is due to the presence of stress concentrators at the substrate–coating interface, as well as the intrinsic characteristics of the coating.
</description>
<pubDate>Tue, 01 Jan 2013 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/9666</guid>
<dc:date>2013-01-01T00:00:00Z</dc:date>
<dc:creator>LA BARBERA-SOSA, J.G.</dc:creator>
<dc:creator>SANTANA, Y.Y.</dc:creator>
<dc:creator>VILLALOBOS-GUTIERREZ, C.</dc:creator>
<dc:creator>CHICOT, Didier</dc:creator>
<dc:creator>LESAGE, J.</dc:creator>
<dc:creator>DECOOPMAN, Xavier</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:creator>STAIA, M.H.</dc:creator>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:description>The fatigue behavior of a SAE 4340 steel, coated with a 50% WC–10Co–4Cr/50% Colmonoy 88 deposit, by high velocity oxygen fuel (HVOF) thermal spray, has been investigated. The change in the maximum alternating stress with the number of cycles to fracture has been described by means of the relationship advanced by Stromeyer. A fractographic analysis has been carried out on some representative fracture surfaces, by means of scanning electron microscopy (SEM) techniques. The mechanical properties of the coating were characterized by means of nanoindentation tests. The results indicate that the coating is highly heterogeneous. Its deposition gives rise to a decrease in the fatigue strength of the substrate of ∼ 30%, in comparison with the uncoated substrate. The decrease in fatigue strength is due to the presence of stress concentrators at the substrate–coating interface, as well as the intrinsic characteristics of the coating.</dc:description>
</item>
<item>
<title>An analysis of the elastic properties of a porous aluminium oxide ﬁlm by means of indentation techniques</title>
<link>http://hdl.handle.net/10985/8554</link>
<description>An analysis of the elastic properties of a porous aluminium oxide ﬁlm by means of indentation techniques
HEMMOUCHE, L.; CHICOT, Didier; AMROUCHE, A.; IOST, Alain; BELOUCHRANI, M.A.; DECOOPMAN, Xavier; LOUIS, G.; PUCHI-CABRERA, Eli-Saul
The elastic modulus of thin ﬁlms can be directly determined by instrumented indentation when the indenter penetration does not exceed a fraction of the ﬁlm thickness, depending on the mechanical properties of both ﬁlm and substrate. When it is not possible, application of models for separating the contribution of the substrate is necessary. In this work, the robustness of several models is analyzed in the case of the elastic modulus determination of a porous aluminium oxide ﬁlm produced by anodization of an aluminium alloy. Instrumented indentation tests employing a Berkovich indenter were performe data nanometric scale, which allowed a direct determination of the ﬁlm elastic modulus, whose value was found to be approximately 11 GPa. However, at a micrometric scale the elastic modulus tends toward the value corresponding to the substrate, of approximately 73 GPa. The objective of the present work is to apply different models for testing their consistency over the complete set of indentation data obtained from both classical tests in microindentation and the continuous stiffness measurement mode in nanoindentation. This approach shows the continuity between the two scales of measurement thus allowing a better representation of the elastic modulus variation between two limits corresponding to the substrate and ﬁlm elastic moduli. Gao's function proved to be the best to represen the elastic modulus variation.
</description>
<pubDate>Tue, 01 Jan 2013 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/8554</guid>
<dc:date>2013-01-01T00:00:00Z</dc:date>
<dc:creator>HEMMOUCHE, L.</dc:creator>
<dc:creator>CHICOT, Didier</dc:creator>
<dc:creator>AMROUCHE, A.</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:creator>BELOUCHRANI, M.A.</dc:creator>
<dc:creator>DECOOPMAN, Xavier</dc:creator>
<dc:creator>LOUIS, G.</dc:creator>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:description>The elastic modulus of thin ﬁlms can be directly determined by instrumented indentation when the indenter penetration does not exceed a fraction of the ﬁlm thickness, depending on the mechanical properties of both ﬁlm and substrate. When it is not possible, application of models for separating the contribution of the substrate is necessary. In this work, the robustness of several models is analyzed in the case of the elastic modulus determination of a porous aluminium oxide ﬁlm produced by anodization of an aluminium alloy. Instrumented indentation tests employing a Berkovich indenter were performe data nanometric scale, which allowed a direct determination of the ﬁlm elastic modulus, whose value was found to be approximately 11 GPa. However, at a micrometric scale the elastic modulus tends toward the value corresponding to the substrate, of approximately 73 GPa. The objective of the present work is to apply different models for testing their consistency over the complete set of indentation data obtained from both classical tests in microindentation and the continuous stiffness measurement mode in nanoindentation. This approach shows the continuity between the two scales of measurement thus allowing a better representation of the elastic modulus variation between two limits corresponding to the substrate and ﬁlm elastic moduli. Gao's function proved to be the best to represen the elastic modulus variation.</dc:description>
</item>
<item>
<title>Tribological response of AA 2024-T3 aluminium alloy coated with a DLC duplex coating</title>
<link>http://hdl.handle.net/10985/9657</link>
<description>Tribological response of AA 2024-T3 aluminium alloy coated with a DLC duplex coating
STAIA, Mariana; PUCHI-CABRERA, Eli-Saul; IOST, Alain; ZAIRI, Amel; BELAYER, S.; VAN GORP, Adrien
Considerable improvement in the tribological response was achieved during sliding wear tests against alumina ball, when AA 2024-T3-aluminium alloy substrate was coated with DLC/NiP duplex coating. Quantitative EPMA analysis carried out on the coated sample cross-section coupled with nanoindentation techniques allowed the identification of the coated system architecture as composed of 4 main layers, with distinct mechanical properties, on top of the aluminium substrate: DLC (a:C-H chromium dopped layer and graded layer of CrC), a newly formed graded layer of CNiPCr, product of the interdifusion during PVD processing, and the NiP coating. The change in the elastic modulus with penetration depth was described by means of an original approach that was developed for its specific application to multilayer coatings.
</description>
<pubDate>Thu, 01 Jan 2015 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/9657</guid>
<dc:date>2015-01-01T00:00:00Z</dc:date>
<dc:creator>STAIA, Mariana</dc:creator>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:creator>ZAIRI, Amel</dc:creator>
<dc:creator>BELAYER, S.</dc:creator>
<dc:creator>VAN GORP, Adrien</dc:creator>
<dc:description>Considerable improvement in the tribological response was achieved during sliding wear tests against alumina ball, when AA 2024-T3-aluminium alloy substrate was coated with DLC/NiP duplex coating. Quantitative EPMA analysis carried out on the coated sample cross-section coupled with nanoindentation techniques allowed the identification of the coated system architecture as composed of 4 main layers, with distinct mechanical properties, on top of the aluminium substrate: DLC (a:C-H chromium dopped layer and graded layer of CrC), a newly formed graded layer of CNiPCr, product of the interdifusion during PVD processing, and the NiP coating. The change in the elastic modulus with penetration depth was described by means of an original approach that was developed for its specific application to multilayer coatings.</dc:description>
</item>
<item>
<title>Sliding Wear Response of Nanostructured YSZ Suspension Plasma-Sprayed Coating</title>
<link>http://hdl.handle.net/10985/9674</link>
<description>Sliding Wear Response of Nanostructured YSZ Suspension Plasma-Sprayed Coating
KOSSMAN, Stephania; CHICOT, Didier; DECOOPMAN, Xavier; IOST, Alain; VAN GORP, Adrien; MEILLOT, E.; PUCHI-CABRERA, Eli-Saul; SANTANA, Y.Y.; STAIA, Mariana
Nanostructured yttria-stabilized zirconia coatings for applications in high-temperature environments can be deposited by suspension plasma spraying (SPS) techniques. The present research has been conducted in order to study the sliding wear response of a SPS ZrO2–8% mol. Y2O3 coating (75 lm in thickness) deposited onto a Haynes 230 substrate, using pin-on-disc tests. Some of the coated samples were subsequently heat-treated for 1 h at 300 and 600 !C. Samples characterization prior and after the wear tests was carried out by SEM, EDS, XRD and optical profilometry techniques. Instrumented indentation was employed to determine elastic modulus and hardness. The results have shown that the as-sprayed and heat-treated samples experienced severe wear (10213 m3/Nm) and the worst wear performance corresponded to the sample heat treated at 600 !C. Such a behavior could be related to both the structural changes that took place during heat treatment and the nature and level of the residual stresses in the coatings. In general, the morphologies of the wear tracks observed by SEM have shown a smoothing of the surface, brittle fracture, smearing and grain pull-out.
</description>
<pubDate>Wed, 01 Jan 2014 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/9674</guid>
<dc:date>2014-01-01T00:00:00Z</dc:date>
<dc:creator>KOSSMAN, Stephania</dc:creator>
<dc:creator>CHICOT, Didier</dc:creator>
<dc:creator>DECOOPMAN, Xavier</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:creator>VAN GORP, Adrien</dc:creator>
<dc:creator>MEILLOT, E.</dc:creator>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:creator>SANTANA, Y.Y.</dc:creator>
<dc:creator>STAIA, Mariana</dc:creator>
<dc:description>Nanostructured yttria-stabilized zirconia coatings for applications in high-temperature environments can be deposited by suspension plasma spraying (SPS) techniques. The present research has been conducted in order to study the sliding wear response of a SPS ZrO2–8% mol. Y2O3 coating (75 lm in thickness) deposited onto a Haynes 230 substrate, using pin-on-disc tests. Some of the coated samples were subsequently heat-treated for 1 h at 300 and 600 !C. Samples characterization prior and after the wear tests was carried out by SEM, EDS, XRD and optical profilometry techniques. Instrumented indentation was employed to determine elastic modulus and hardness. The results have shown that the as-sprayed and heat-treated samples experienced severe wear (10213 m3/Nm) and the worst wear performance corresponded to the sample heat treated at 600 !C. Such a behavior could be related to both the structural changes that took place during heat treatment and the nature and level of the residual stresses in the coatings. In general, the morphologies of the wear tracks observed by SEM have shown a smoothing of the surface, brittle fracture, smearing and grain pull-out.</dc:description>
</item>
<item>
<title>A description of the composite elastic modulus of multilayer coated systems</title>
<link>http://hdl.handle.net/10985/9658</link>
<description>A description of the composite elastic modulus of multilayer coated systems
PUCHI-CABRERA, Eli-Saul; STAIA, M.H.; IOST, Alain
The evaluation of the elastic response of coated systems under indentation loading represents a crucial issue, which determines the behavior of such systems under tribological applications. Although a number of models have been proposed in the literature for the description of the change in the composite modulus with indentation depth, as well as for the determination of the elastic modulus of monolayer coatings, only few works address the analysis of multilayer coatings. The present work proposes a general methodology, which allows the modification and extension of the models employed in the analysis of monolayer coatings, for the study of the elastic response of multilayer coatings. For this purpose, a number of models have been examined, including those proposed by Gao et al., Menčík et al., Perriot and Barthel, Antunes et al., Korsunsky and Constantinescu, Doerner and Nix, Bec et al. and Bull. The foundation of the advanced formalism is the physically-based concept proposed by Iost et al. for the computation of the volume fraction of each layer in the coating and therefore, of its contribution to the global elastic response under indentation. The modified models are further employed in the analysis of a coated system composed of a 2024-T6 aluminum alloy substrate coated with a multilayer coating of DLC/CrC/CNiPCr/NiP of approximately 54 μm in thickness, as well as, a set of experimental data reported by Bull for a bilayer coated system. It has been shown that the different models analyzed are able to provide a satisfactory description of the experimental data, although the quality of the fit depends on the number of material parameters involved in each model. The mean square error of the fit is employed for conducting a comparison between the models.
</description>
<pubDate>Thu, 01 Jan 2015 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/9658</guid>
<dc:date>2015-01-01T00:00:00Z</dc:date>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:creator>STAIA, M.H.</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:description>The evaluation of the elastic response of coated systems under indentation loading represents a crucial issue, which determines the behavior of such systems under tribological applications. Although a number of models have been proposed in the literature for the description of the change in the composite modulus with indentation depth, as well as for the determination of the elastic modulus of monolayer coatings, only few works address the analysis of multilayer coatings. The present work proposes a general methodology, which allows the modification and extension of the models employed in the analysis of monolayer coatings, for the study of the elastic response of multilayer coatings. For this purpose, a number of models have been examined, including those proposed by Gao et al., Menčík et al., Perriot and Barthel, Antunes et al., Korsunsky and Constantinescu, Doerner and Nix, Bec et al. and Bull. The foundation of the advanced formalism is the physically-based concept proposed by Iost et al. for the computation of the volume fraction of each layer in the coating and therefore, of its contribution to the global elastic response under indentation. The modified models are further employed in the analysis of a coated system composed of a 2024-T6 aluminum alloy substrate coated with a multilayer coating of DLC/CrC/CNiPCr/NiP of approximately 54 μm in thickness, as well as, a set of experimental data reported by Bull for a bilayer coated system. It has been shown that the different models analyzed are able to provide a satisfactory description of the experimental data, although the quality of the fit depends on the number of material parameters involved in each model. The mean square error of the fit is employed for conducting a comparison between the models.</dc:description>
</item>
<item>
<title>Sliding wear resistance of thermal sprayed wc-12co coatings reinforced with carbon nanotubes</title>
<link>http://hdl.handle.net/10985/11954</link>
<description>Sliding wear resistance of thermal sprayed wc-12co coatings reinforced with carbon nanotubes
SANTANA, Y.Y.; GUTIÉRREZ, M.V.; STAIA, Mariana; LA BARBERA-SOSA, J.G.; PUCHI-CABRERA, Eli-Saul; IOST, Alain; CHICOT, Didier
Thermal sprayed coatings based on WC-Co are widely used for providing wear resistance to engineering components. The High Velocity Oxygen Fuel (HVOF) thermal spraying technique is one of the most commonly employed for depositing wear resistant coatings on steel substrates and constitutes one of the coating processes that have been technically validated for the replacement of electrolytic hard chrome (EHC) coatings, especially for extreme operating conditions. The present work aims at studying the tribological behavior, under sliding wear conditions, of a coating based on WC-12Co, with and without the reinforcement of carbon nanotubes (CNTs). The coating has been deposited by HVOF thermal spraying on a SAE 1045 substrate steel. Wear tests were carried out under the ball-on-disk configuration, at a constant sliding velocity of ∼ 0.2 m.s-1 and an applied load of 10 N, employing WC-6Co balls as static counterparts. The results for the CNTs reinforced coating have shown a decrease of ∼ 58% and 86% in the values of the average friction coefficient and wear rate, respectively, as compared with the conventional coatings. The observed wear mechanism was mainly of an abrasive type.
</description>
<pubDate>Sun, 01 Jan 2017 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/11954</guid>
<dc:date>2017-01-01T00:00:00Z</dc:date>
<dc:creator>SANTANA, Y.Y.</dc:creator>
<dc:creator>GUTIÉRREZ, M.V.</dc:creator>
<dc:creator>STAIA, Mariana</dc:creator>
<dc:creator>LA BARBERA-SOSA, J.G.</dc:creator>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:creator>CHICOT, Didier</dc:creator>
<dc:description>Thermal sprayed coatings based on WC-Co are widely used for providing wear resistance to engineering components. The High Velocity Oxygen Fuel (HVOF) thermal spraying technique is one of the most commonly employed for depositing wear resistant coatings on steel substrates and constitutes one of the coating processes that have been technically validated for the replacement of electrolytic hard chrome (EHC) coatings, especially for extreme operating conditions. The present work aims at studying the tribological behavior, under sliding wear conditions, of a coating based on WC-12Co, with and without the reinforcement of carbon nanotubes (CNTs). The coating has been deposited by HVOF thermal spraying on a SAE 1045 substrate steel. Wear tests were carried out under the ball-on-disk configuration, at a constant sliding velocity of ∼ 0.2 m.s-1 and an applied load of 10 N, employing WC-6Co balls as static counterparts. The results for the CNTs reinforced coating have shown a decrease of ∼ 58% and 86% in the values of the average friction coefficient and wear rate, respectively, as compared with the conventional coatings. The observed wear mechanism was mainly of an abrasive type.</dc:description>
</item>
<item>
<title>Surface Modification Technologies</title>
<link>http://hdl.handle.net/10985/11760</link>
<description>Surface Modification Technologies
STAIA, Mariana; TROCELIS, A; ZAIRI, Amel; SUAREZ, M; PUCHI-CABRERA, Eli-Saul; IOST, Alain; MONTAGNE, Alex
The present work has been conducted in order to assess the mechanical and tribological performance of a ZrN coating deposited onto a H13 steel substrate by means of a closed field unbalanced magnetron-sputtering ion-plating (CFUMSIP) process. The hardness and elastic modulus of the coated system have been determined by means of nanoindentation techniques. Dry and wet sliding wear tests, employing a tribometer under a ball-on-disc configuration, were carried out making use of an alumina ball as counterpart, with an applied normal load of 2 N at a constant speed of 5 cm/s. For the wet wear tests, a 3.5 wt% NaCl solution was used. The resulting wear scars were analyzed by means of both SEM and optical profilometry techniques. It has been determined that, during testing under the corrosive solution, the coating experiences a severe abrasive wear mechanism, due to the combined action of the alumina ball, the hard “debris” and the phenomenon of crevice corrosion. On the other hand, it has also been shown that the coated system is able to increase the wear resistance of the substrate by more than one order of magnitude, if the wear tests are carried out in air under the same conditions.
</description>
<pubDate>Fri, 01 Jan 2016 00:00:00 GMT</pubDate>
<guid isPermaLink="false">http://hdl.handle.net/10985/11760</guid>
<dc:date>2016-01-01T00:00:00Z</dc:date>
<dc:creator>STAIA, Mariana</dc:creator>
<dc:creator>TROCELIS, A</dc:creator>
<dc:creator>ZAIRI, Amel</dc:creator>
<dc:creator>SUAREZ, M</dc:creator>
<dc:creator>PUCHI-CABRERA, Eli-Saul</dc:creator>
<dc:creator>IOST, Alain</dc:creator>
<dc:creator>MONTAGNE, Alex</dc:creator>
<dc:description>The present work has been conducted in order to assess the mechanical and tribological performance of a ZrN coating deposited onto a H13 steel substrate by means of a closed field unbalanced magnetron-sputtering ion-plating (CFUMSIP) process. The hardness and elastic modulus of the coated system have been determined by means of nanoindentation techniques. Dry and wet sliding wear tests, employing a tribometer under a ball-on-disc configuration, were carried out making use of an alumina ball as counterpart, with an applied normal load of 2 N at a constant speed of 5 cm/s. For the wet wear tests, a 3.5 wt% NaCl solution was used. The resulting wear scars were analyzed by means of both SEM and optical profilometry techniques. It has been determined that, during testing under the corrosive solution, the coating experiences a severe abrasive wear mechanism, due to the combined action of the alumina ball, the hard “debris” and the phenomenon of crevice corrosion. On the other hand, it has also been shown that the coated system is able to increase the wear resistance of the substrate by more than one order of magnitude, if the wear tests are carried out in air under the same conditions.</dc:description>
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