Polyoxymethylene additives
Chapitre d'ouvrage scientifique
Résumé
This chapter presents a review of the role of several additives on POM processing (lubricating agents, processing aids, nucleating agents), performances (fillers, impact modifiers) and lifetime increase (antioxidants, compounds reacting with secondary reaction products such as acids scavengers, UV stabilizers and flame retardants) and aspect properties (pigments). It is tried to review existing models permitting to describe the efficiency of these additives in POM and predict the effect of other comparable additives that are not included in this review. Last, since POM compounding can be relatively complex and additives are scarcely used alone, it was also tried to report some side effects of these additives and the possible synergistic or antagonistic effects in the case of combinations of additives.
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Article dans une revue avec comité de lectureOKAMBA-DIOGO, Octavie; VERDU, Jacques; FERNAGUT, François; GUILMENT, Jean;
FAYOLLE, Bruno;
RICHAUD, Emmanuel (Elsevier, 2014)
The present article reports a study of thermal oxidation of unstabilized polyamide 11 films at several temperatures (90–165 °C) under atmospheric pressure and under various oxygen pressures (up to 1.6 MPa) at 110 °C. The ... -
Article dans une revue avec comité de lectureA general kinetic model for the photothermal oxidation of polypropylene has been derived from the basic auto-oxidation mechanistic scheme in which the main sources of radicals are the thermolysis and photolysis of the most ...
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Article dans une revue avec comité de lectureA statistical theory was proposed for the degradation (random scission of chains) of a network having f-functional nodes in the case where all chains contain equireactive groups and a chain scission event does not create ...
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Article dans une revue avec comité de lectureThe hydrolysis of almost ideal networks based on macrodiols of average molar mass about 2 kg mol 1, with L¼18 ester groups per chain is studied. Tensile testing is used to evaluate the crosslink density through the statistical ...
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Article dans une revue avec comité de lectureOKAMBA-DIOGO, Octavie; VERDU, Jacques; FERNAGUT, François; GUILMENT, Jean;
FAYOLLE, Bruno;
RICHAUD, Emmanuel (Elsevier, 2015)
The oxidation kinetics of unstabilized polyamide 11 thin film under oxygen pressures up to 2.0 MPa was studied by means of ferrous ion method for hydroperoxides titration, size exclusion chromatography (SEC) for molar weight ...
