Tensile properties of polyproylene fibres
Chapitre d'ouvrage scientifique
Date
2009Résumé
As soon as it appeared on the market, one half century ago, polypropylene (PP) appeared as a promising fibre-forming polymer but with some difficulties in processing due to a lack of control of its viscoelastic properties and in durability due to its low stability to oxidation. These difficulties were progressively resolved in the last decades by a sharper control of synthesis conditions e.g. of stereoregularity and molar mass distribution, and by a better knowledge of oxidation and stabilization mechanisms. These research efforts allowed PP to invade a very wide range of fibre applications, from disposable diapers to geotextiles.
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Article dans une revue avec comité de lectureDJOUANI, Fatma; VERDU, Jacques; FLACONNECHE, Bruno; FAYOLLE, Bruno; RICHAUD, Emmanuel (Institut Français du Pétrole, 2015)This paper deals with polymer-fuel interaction focusing on specific effects of biofuels on polyethylene (PE) in automotive applications. The practical objective is to develop a predictable approach for durability of ...
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Article dans une revue avec comité de lectureOKAMBA-DIOGO, Octavie; VERDU, Jacques; FERNAGUT, François; GUILMENT, Jean; FAYOLLE, Bruno; RICHAUD, Emmanuel (Elsevier, 2015)The oxidation kinetics of unstabilized polyamide 11 thin film under oxygen pressures up to 2.0 MPa was studied by means of ferrous ion method for hydroperoxides titration, size exclusion chromatography (SEC) for molar weight ...
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Article dans une revue avec comité de lectureOKAMBA-DIOGO, Octavie; VERDU, Jacques; FERNAGUT, François; GUILMENT, Jean; FAYOLLE, Bruno; RICHAUD, Emmanuel (Elsevier, 2014)The present article reports a study of thermal oxidation of unstabilized polyamide 11 films at several temperatures (90–165 °C) under atmospheric pressure and under various oxygen pressures (up to 1.6 MPa) at 110 °C. The ...
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Article dans une revue avec comité de lectureThis article deals with polypropylene stabilization by hindered 2,6-di-tert-butylphenols. Two aspects are mainly considered: the influence of stabilizer structure, of its concentration and temperature on induction period ...
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Co-oxidation kinetic model for the thermal oxidation of polyethylene-unsaturated substrate systems Article dans une revue avec comité de lectureThe thermal oxidation of polyethylene (PE) impregnated by the methyl esters of unsaturated fatty acids (UFEs) was studied using chemiluminescence, and infra-red spectrophotometry. It was shown that the presence of UFEs ...