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Reduced physical aging rates of polylactide in polystyrene/polylactide multilayer films from fast scanning calorimetry

Article dans une revue avec comité de lecture
Author
MONNIER, Xavier
970 Groupe de physique des matériaux [GPM]
FERNANDES NASSAR, Samira
135726 Ingénierie Procédés Aliments [GENIAL]
DOMENEK, Sandra
135726 Ingénierie Procédés Aliments [GENIAL]
419361 Université Paris-Saclay
GUINAULT, Alain
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
SOLLOGOUB, Cyrille
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
DARGENT, Eric
970 Groupe de physique des matériaux [GPM]
DELPOUVE, Nicolas
970 Groupe de physique des matériaux [GPM]

URI
http://hdl.handle.net/10985/13875
DOI
10.1016/j.polymer.2018.07.017
Date
2018
Journal
Polymer

Abstract

The physical aging behavior of amorphous polylactide constrained against polystyrene in layers of 300 nm, thanks to the layer–multiplying co–extrusion process, was investigated by fast–scanning calorimetry (FSC). By cooling down the sample from the liquid state to the glassy one at very fast scanning rates, it was possible to investigate the structural relaxation of the polymer glass at high temperatures for which the time needed to reach the equilibrium was shortened. Therefore it was possible to perform the study of physical aging in experimental conditions providing an expanded view of the structural relaxation for short aging times. Taking benefit of this property, it was highlighted that the aging kinetics of polylactide occurred significantly slower in the multilayer film, in comparison with a bulk amorphous film. The process of recovery in the multilayer system was found to occur at similar rates, or even slower, than in a three–layer film in which polylactide reached its maximum extent of crystallinity. This was attributed to mobility hindrance that might be inherent to the extrusion conditions or associated with the presence of capped interfaces with polystyrene.

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