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Introducing Functionality to Fluorinated Electroactive Polymers

Article dans une revue avec comité de lecture
Author
KALLITSIS, Konstantinos
247140 Laboratoire de Chimie des Polymères Organiques [LCPO]
469281 Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
SOULESTIN, Thibaut
46191 Piezotech SAS [Piezotech SAS]
TENCÉ-GIRAULT, Sylvie
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
486315 Arkema [Arkema]
BROCHON, Cyril
247140 Laboratoire de Chimie des Polymères Organiques [LCPO]
469281 Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CLOUTET, Éric
247140 Laboratoire de Chimie des Polymères Organiques [LCPO]
469281 Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
DOMINGUES-DOS SANTOS, Fabrice
46191 Piezotech SAS [Piezotech SAS]
HADZIIOANNOU, Georges
247140 Laboratoire de Chimie des Polymères Organiques [LCPO]

URI
http://hdl.handle.net/10985/17957
DOI
10.1021/acs.macromol.9b01942
Date
2019
Journal
Macromolecules

Abstract

Fluorinated electroactive polymers (FEPs) are among the most interesting insulating materials for the production of organic electronic devices. Their ability to tune their response to an applied electric field makes them appropriate for vastly different applications in electronics. However, due to the chemical inertness of such polymers and the rather complex synthetic processes required for their production, introducing additional functionality to FEPs remains an open challenge. Here, we present a facile way to introduce additional functionality to FEPs and more specifically photopatternability by a simple etherification method, which allows us to introduce almost any functional group on FEPs. Photo-cross-linkable moieties were introduced on FEPs using this method, inducing photopatternability, while tuning their electroactive response with great property enhancement up to 60% in terms of relative permittivity in several cases.

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