Oxidative Ageing of Polymers
Ouvrage scientifique
Abstract
This book aims to rehabilitate kinetic modeling in the domain of polymer ageing, where it has been almost abandoned by the research community. Kinetic modeling is a key step for lifetime prediction, a crucial problem in many industrial domains in which needs cannot be satisfied by the common empirical methods. The book proposes a renewed approach of lifetime prediction in polymer oxidative ageing. This approach is based on kinetic models built from relatively simple mechanistic schemes but integrating physical processes (oxygen diffusion and stabilizer transport), and use property (for instance mechanical failure) changes. An important chapter is dedicated to radiation-induced oxidation and its most important applications: radiochemical ageing at low dose rates and photo-chemical ageing under solar radiation. There is also a chapter devoted to the problem of ageing under coupled oxidation and mechanical loading. (Extract from the web site of the publisher)
Files in this item
- Name:
- PIMM_BOOK_2013_VERDU.pdf
- Size:
- 302.2Kb
- Format:
- Description:
- ouvrages scientifiques
Related items
Showing items related by title, author, creator and subject.
-
Article dans une revue avec comité de lectureLAFARIE, Marie Christine; GRANDIDIER, Jean Claude; OLIVIER, Loic; VERDU, Jacques; CINQUIN, Jacques;
COLIN, Xavier (Elsevier, 2010)
The present paper presents a review of the main activities carried out within the context of the COMEDI research program, a joint collaboration involving three research teams focusing on the thermo-oxidation behaviour of ... -
Article dans une revue avec comité de lectureThis article deals with polypropylene stabilization by hindered 2,6-di-tert-butylphenols. Two aspects are mainly considered: the influence of stabilizer structure, of its concentration and temperature on induction period ...
-
Chapitre d'ouvrage scientifiqueAs soon as it appeared on the market, one half century ago, polypropylene (PP) appeared as a promising fibre-forming polymer but with some difficulties in processing due to a lack of control of its viscoelastic properties ...
-
Article dans une revue avec comité de lectureThermal aging of thin films of unstabilized polydicyclopentadiene (pDCPD) at several temperatures ranging from 120 to 30 C was investigated by means of carbonyl build up by FTIR with ammonia derivatization, double bond ...
-
Co-oxidation kinetic model for the thermal oxidation of polyethylene-unsaturated substrate systems Article dans une revue avec comité de lectureThe thermal oxidation of polyethylene (PE) impregnated by the methyl esters of unsaturated fatty acids (UFEs) was studied using chemiluminescence, and infra-red spectrophotometry. It was shown that the presence of UFEs ...