Thermal oxidation of poly(dicyclopentadiene) - Effect of phenolic and hindered amine stabilizers
Article dans une revue avec comité de lecture
The thermal oxidation of stabilized polydicyclopentadiene was deeply studied here for the first time. Three kinds of antioxidants (phenolic antioxidant BHT, monomeric hindered amine in alkoxylated form Tinuvin 123 and oligomeric hindered amine Chimassorb 2020) were compared at the same concentrations. Tinuvin 123 was observed to me more efficient than Chimassorb 2020 because of the “activated” nature of alkoxyamine in Tinuvin 123. Results were simulated using a completed version of previously established kinetic model for thin PDCPD films in order to be able to make reliable lifetime prediction of stabilized PDCDP.
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Article dans une revue avec comité de lectureHUANG, Jing; DAVID, Adelina; LE GAC, Pierre-Yves; LORTHIOIR, Cédric; COELHO, Cristina; RICHAUD, Emmanuel (Elsevier, 2019)This paper reports chemical changes that occur in polydicyclopentadiene during thermal oxidation at several temperatures and oxygen pressures. A particular attention was paid to the double bond consumption since these ...
Article dans une revue avec comité de lectureHUANG, Jing; MINNE, Wendy; DROZDZAK, Renata; RECHER, Gilles; LE GAC, Pierre Yves; RICHAUD, Emmanuel (Elsevier, 2020)Thin unstabilized PDCPD film were thermally oxidized in ovens at several temperatures ranging from 50 °C to 120 °C. Hydroperoxide concentration was monitored by DSC. It was observed that hydroperoxides concentration reaches ...
Impact of thermal oxidation on mechanical behavior of polydicylopentadiene: Case of non-diffusion limited oxidation Article dans une revue avec comité de lectureDAVID, Adelina; HUANG, Jing; RICHAUD, Emmanuel; YVES LE GAC, Pierre (Elsevier, 2020)Impact of thermal oxidation on mechanical behavior of polydicyclopentadiene (pDCPD) is studied in this paper. Thermal oxidation is performed over a wide range of ageing temperature, from 20 °C to 120 °C using 60 μm thin ...
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