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Thermal oxidation of poly(dicyclopentadiene) - Effect of phenolic and hindered amine stabilizers

Article dans une revue avec comité de lecture
Author
HUANG, Jing
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
YVES LE GAC, Pierre
85396 Systèmes Sous-Marins [SM]
RICHAUD, Emmanuel
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]

URI
http://hdl.handle.net/10985/19928
DOI
10.1016/j.polymdegradstab.2020.109267
Date
2021
Journal
Polymer Degradation and Stability

Abstract

The thermal oxidation of stabilized polydicyclopentadiene was deeply studied here for the first time. Three kinds of antioxidants (phenolic antioxidant BHT, monomeric hindered amine in alkoxylated form Tinuvin 123 and oligomeric hindered amine Chimassorb 2020) were compared at the same concentrations. Tinuvin 123 was observed to me more efficient than Chimassorb 2020 because of the “activated” nature of alkoxyamine in Tinuvin 123. Results were simulated using a completed version of previously established kinetic model for thin PDCPD films in order to be able to make reliable lifetime prediction of stabilized PDCDP.

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