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Improvement of the self‐assembly of low χ ABA triblock copolymers with the addition of an ionic liquid

Article dans une revue avec comité de lecture
Author
ccGULIYEVA, Aynur
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
PUNG, Hélène
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
TENCE-GIRAULT, Sylvie
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
486315 Arkema [Arkema]
ccRÉBILLAT, Marc
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
ccSERGHEI, Anatoli
203996 Ingénierie des Matériaux Polymères [IMP]
ccGERVAIS, Matthieu
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
ccSOLLOGOUB, Cyrille
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]
ccROLAND, Sébastien
86289 Laboratoire Procédés et Ingénierie en Mécanique et Matériaux [PIMM]

URI
http://hdl.handle.net/10985/23360
DOI
10.1002/pi.6476
Date
2022-11
Journal
Polymer International

Abstract

Self-assembly of high molecular weight commercially available low χ ABA triblock copolymers with ionic liquids (ILs) was observed after solvent casting without the implementation of an additional annealing step. Here, the addition of an IL to a tri- block copolymer poly(methyl methacrylate-b-butyl acrylate-b-methyl methacrylate) (MAM) with an elastomeric central block and rigid end blocks is proposed to tune the self-assembled morphology. Two different compositions of this copolymer with different initial microstructures (ill-defined morphology without long-range order and a lamellar morphology) were selected. The selectivity of the IL addition in one of the block phases was studied through the evolution of the glass transition of both blocks. The impact of the IL weight concentration on the morphology as well as the domain spacing is presented. Adding IL to the first copolymer detected a lyotropic disorder–order transition towards a gyroid morphology, observed even for a high molecular weight copolymer due to the low χ parameter, and for higher IL content a second transition to a lamellar morphology was observed. For the second copolymer, only an order–order transition (lamellae to cylinders) could be detected at high IL content. IL also enhanced the long-range ordering of the MAM morphology obtained through solvent casting without addi- tional annealing steps, compared with the same composition without IL.

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